Encapsulated chloride coordinating with two in-in protons of bridgehead amines in an octaprotonated azacryptand.
نویسندگان
چکیده
An encapsulated chloride in a thiophene-based cryptand is bridged by two in-in protons of tertiary amines with an N...Cl(-) distance of 3.048(3) A, similar to that observed in Park and Simmons' katapinand chloride complex.
منابع مشابه
Unusual bridging of three nitrates with two bridgehead protons in an octaprotonated azacryptand.
Structural analysis of the nitrate complex of a thiophene-based azacryptand suggests that three nitrates are bridged with two bridgehead protons which play the topological role of two transition metal ions in a classical Werner type coordination complex bridging three anions.
متن کاملMethod of Production and Assessment of an Encapsulated Choline Chloride and Its Effects on Growth Performanc and Serum Lipid Indices in Broilers
Since, choline chloride caking causes serious operating difficulties and customer complaints, two experiments were conducted to optimize in vitro production of a novel encapsulated choline chloride (ECC) with minimum hygroscopic property and optimize delivery in gastrointestinal tract (GIT). The in vivo verification test of ECC was used to compare it with the commercial choline chloride (CC) in...
متن کاملOne-pot highly efficient synthesis of substituted pyrroles and N-bridgehead pyrroles by zinc-catalyzed multicomponent reaction.
A convenient zinc(II) chloride-catalyzed regioselective propargylation/amination/cycloisomerization process has been developed for the synthesis of substituted pyrrole derivatives from propargylic acetates, enoxysilanes and primary amines. Various aromatic and aliphatic propargylic acetates participate well in the reaction, providing the propargylation/amination/cycloisomerization products in g...
متن کاملLITHIUM PERCHLORATE MEDIATED AMINATION REACTION OF ALDEHYDES: A NOVEL METHOD FOR SYNTHESIS OF N, N-DIALKYL-p-SILYLATED AMINES*
P-Silylated N,N-dialkyl amines (5) were easily synthesized in good to excellent yield from aldehydes (1), trimethylsilyldialkylamines (2), and trimethylsilylmethylmagnesium chloride (4) in the presence of 5 M lithium perchlorate solution in diethyl ether. The reaction Of (2) with aldehyde proceeded smoothly in the LiCI0 , to give the imimum salt (3). Addition of trimethylsilylmethylrnagnes...
متن کاملStructural studies on encapsulation of tetrahedral and octahedral anions by a protonated octaaminocryptand cage
Structural aspects of the binding of inorganic anions such as perchlorate, hydrogen sulfate, and hexafluorosilicate with the proton cage of octaaminocryptand L(1), N(CH(2)CH(2)NHCH(2)-p-xylyl-CH(2)NHCH(2)CH(2))(3)N), are examined thoroughly. Crystallographic results for a hexaprotonated perchlorate complex of L(1), [(H(6)L(1))(6+)(ClO(4) (-))]5(ClO(4) (-)).11H(2)O.CH(3)CN (1), an octaprotonated...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 42 شماره
صفحات -
تاریخ انتشار 2009